Câu2.2:
Gọi nồng độ A,B là x,y
TN1--Cần [imath]H_2SO_4[/imath] trung hòa ~> NaOH dư
n HCl=0,15x ; n NaOH=0,25y ; n [imath]H_2SO_4[/imath]=0,0325
[imath]NaOH+HCl \rightarrow NaCl+H_2O[/imath]
0,15x---0,15x
[imath]2NaOH+H_2SO_4 \rightarrow Na_2SO_4+2H_2O[/imath]
0,25y-0,15x---(0,25y-0,15x)0,5
(0,25y-0,15x)0,5=0,0325(1)
TN2--Cần KOH trung hòa ~> HCl dư
n KOH=0,025 ; n HCl=0,25x ; n NaOH=0,15y
[imath]NaOH+HCl \rightarrow NaCl+H_2O[/imath]
0,15y---0,15y
[imath]HCl+KOH \rightarrow KCl+H_2O[/imath]
0,25x-0,15y---0,25x-0,15y
0,25x-0,15y=0,025(2)
(1)(2)=>x=0,4=> [imath]C_M[/imath] HCl=0,4M ; y=0,5=> [imath]C_M[/imath] NaOH=0,5M
Câu 3.2
[imath]Na+H_2O \rightarrow NaOH+\frac{1}{2}H_2[/imath]
x-------------------------------0,5x
[imath]R+2H_2O \rightarrow R(OH)_2+H_2[/imath]
y-----------------------------------y
x=2,5y ; 0,5x+y=0,0675
=>x=0,075, y=0,03
BTKL=> [imath]m_R[/imath]=1,2=>R=40(Ca)
BT Ca =>[imath]n_{Ca(OH)_2}[/imath]=0,03
BT Na=>[imath]n_{NaOH}[/imath]=0,075
[imath]n_{CO_2}=0,115[/imath]
[imath]Ca(OH)_2+CO_2 \rightarrow CaCO_3+H_2O[/imath]
0,03-----------0,03------------0,03
[imath]2NaOH+CO_2 \rightarrow Na_2CO_3 + H_2O[/imath]
0,075----0,0375--------------0,0375
[imath]Na_2CO_3+CO_2+H_2O \rightarrow 2NaHCO_3[/imath]
0,0375-------0,0375
[imath]CaCO_3+H_2O+CO_2 \rightarrow Ca(HCO_3)_2[/imath]
0,01---------------0,01
[imath]m_{kt}=(0,03-0,01).100=2g[/imath]
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