$n_{KOH}$=0,3mol=>$n_{K^+}=0,3mol$
gọi CT muối $K_kH_{2-k}CO_3$
$kKOH+CO_2 \rightarrow K_kH_{2-k}CO_3 + (k-1)H_2O $
0,3-------------------------------0,3/k
$M_{muối}=39k+2-k+60=38k+62 $
Mặt khác :$M_{muối}=\frac{26,9}{0,3/k}=89,7k$
=>89,7k=38k+62=>k=1,2
1<k<2 => muối gồm $CO_3^{2-}$ và $HCO_3^-$
$2OH^- + CO_2 \rightarrow CO_3^{2-} + H_2O$
0,3----------0,15------------------0,15
$CO_3^{2-}+CO_2+H_2O \rightarrow 2HCO3^-$
x-------------------x------------------------2x
$m_{muối}=(0,15-x).60+2x.61+39.0,3=26,9$
=>x=0,1=>$n_{CO_2}$=x+0,15=0,15+0,1=0,25=>V=5,6l